It doesn’t give the character name on the cards but the foldoutable booklet/leaflet does.

Here are some:

Fool - Frodo
Magician - Gandalf
High priestess - Galadriel
Empress - Arwen
Emperor - Aragorn
Hierophant - Elrond
Lovers - Arwen & Aragorn
Chariot - Samwise
Strength - Gimli
Hermit - Bilbo
Wheel - The Shire
Justice - Legolas
Hanged Man - Gollum
Death - Mount Doom
Temperance - Celeborn
Devil - Witch King of Angmar
Tower - Barad-dur
Star - Arwen’s Necklace
Moon - Galadriel’s Mirror
Sun - Eowyn
Judgement - Horn of Gondor
World - The Fellowship

That’s all the major arcana. Many of the minor arcana are also named characters, including Rosie, Faramir and others.